To Jabroni
When Win32diskimager makes the live kali-linux usb the process is automatic.
You have stated the live install doesnot work.
Possibly your kali-linux iso file is corrupted try downloading again.
What is the size of your usb flash drive? You probably should use at least a 8 gig flash drive if you want to install the persistent feature
Is your BIOS setup to read from the flash drive at the start of the boot process?
MTeams